Looked at the logs and the iOS log does show it trying to get through to the url you did the nslookup for
2019/01/20 18:14:08.150 (74 MB) (254369) 🔧 PMKConnectionTestOperation.m:51 | Testing connection <PMKPlexServerConnection: 0x282fa46e0>[ https://192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 - 192.168.0.195:32400 (plex,published,direct) ] to standard server GamingPC - 66b4f515378494619a7373873b677a0a94fd007b
2019/01/20 18:14:08.154 (74 MB) (254369) 🔧 PMKConnectionTestOperation.m:51 | Testing connection <PMKPlexServerConnection: 0x282fa4c30>[ https://192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 - 192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 (plex,published,direct) ] to standard server GamingPC - 66b4f515378494619a7373873b677a0a94fd007b
2019/01/20 18:14:08.161 (74 MB) (254369) 🔧 PMKConnectionTestOperation.m:51 | Testing connection <PMKPlexServerConnection: 0x282f598b0>[ https://192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 - 192.168.0.195:32400 (plex,discovered,direct) ] to standard server GamingPC - 66b4f515378494619a7373873b677a0a94fd007b
2019/01/20 18:14:08.165 (74 MB) (254369) 🔧 PMKConnectionTestOperation.m:51 | Testing connection <PMKPlexServerConnection: 0x282f59c20>[ https://192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 - 192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 (plex,discovered,direct) ] to standard server GamingPC - 66b4f515378494619a7373873b677a0a94fd007b
2019/01/20 18:14:23.282 (112 MB) (254553) ❌ PMKConnectionTestOperation.m:58 | Failed testing connection <PMKPlexServerConnection: 0x282f598b0>[ https://192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 - 192.168.0.195:32400 (plex,discovered,direct) ] to standard server GamingPC (hasPresence) - 66b4f515378494619a7373873b677a0a94fd007b with error Error Domain=NSURLErrorDomain Code=-1001 "The request timed out." UserInfo={_kCFStreamErrorCodeKey=-2102, NSUnderlyingError=0x2802583f0 {Error Domain=kCFErrorDomainCFNetwork Code=-1001 "(null)" UserInfo={_kCFStreamErrorCodeKey=-2102, _kCFStreamErrorDomainKey=4}}, _NSURLErrorFailingURLSessionTaskErrorKey=LocalDataTask <8C50AC3C-F118-42B3-8E67-792A85AEA8E4>.<1>, _NSURLErrorRelatedURLSessionTaskErrorKey=(
2019/01/20 18:14:23.286 (112 MB) (254330) ❌ PMKConnectionTestOperation.m:58 | Failed testing connection <PMKPlexServerConnection: 0x282f59c20>[ https://192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 - 192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 (plex,discovered,direct) ] to standard server GamingPC (hasPresence) - 66b4f515378494619a7373873b677a0a94fd007b with error Error Domain=NSURLErrorDomain Code=-1001 "The request timed out." UserInfo={_kCFStreamErrorCodeKey=-2102, NSUnderlyingError=0x2802a5e90 {Error Domain=kCFErrorDomainCFNetwork Code=-1001 "(null)" UserInfo={_kCFStreamErrorCodeKey=-2102, _kCFStreamErrorDomainKey=4}}, _NSURLErrorFailingURLSessionTaskErrorKey=LocalDataTask <6C7B3FF1-7F73-44CB-9EFA-5C441DC21E5A>.<1>, _NSURLErrorRelatedURLSessionTaskErrorKey=(
2019/01/20 18:14:23.286 (112 MB) (254551) ❌ PMKConnectionTestOperation.m:58 | Failed testing connection <PMKPlexServerConnection: 0x282fa46e0>[ https://192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 - 192.168.0.195:32400 (plex,published,direct) ] to standard server GamingPC (hasPresence) - 66b4f515378494619a7373873b677a0a94fd007b with error Error Domain=NSURLErrorDomain Code=-1001 "The request timed out." UserInfo={_kCFStreamErrorCodeKey=-2102, NSUnderlyingError=0x2802a7570 {Error Domain=kCFErrorDomainCFNetwork Code=-1001 "(null)" UserInfo={_kCFStreamErrorCodeKey=-2102, _kCFStreamErrorDomainKey=4}}, _NSURLErrorFailingURLSessionTaskErrorKey=LocalDataTask <0E09891D-37FF-48BA-8EAF-DC9BE9982FA9>.<1>, _NSURLErrorRelatedURLSessionTaskErrorKey=(
2019/01/20 18:14:23.287 (112 MB) (254552) ❌ PMKConnectionTestOperation.m:58 | Failed testing connection <PMKPlexServerConnection: 0x282fa4c30>[ https://192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 - 192-168-0-195.02f522da765c4d719da970c046c9a837.plex.direct:32400 (plex,published,direct) ] to standard server GamingPC (hasPresence) - 66b4f515378494619a7373873b677a0a94fd007b with error Error Domain=NSURLErrorDomain Code=-1001 "The request timed out." UserInfo={_kCFStreamErrorCodeKey=-2102, NSUnderlyingError=0x2802a7630 {Error Domain=kCFErrorDomainCFNetwork Code=-1001 "(null)" UserInfo={_kCFStreamErrorCodeKey=-2102, _kCFStreamErrorDomainKey=4}}, _NSURLErrorFailingURLSessionTaskErrorKey=LocalDataTask <47835C4F-0430-4F01-B98F-4404FD9C15B7>.<1>, _NSURLErrorRelatedURLSessionTaskErrorKey=(
You could enable the firewall logging on the PC and see if the requests are being dropped
The other area to look at is AP Isolation in the router - in case wifi is isolated from ethernet
What firewall is in use?
Add an inbound tcp rule
Protocol = tcp
local port = 32400
remote port = any
remote ip = any
action = allow
I have not read all the posts - i presume you checked that network connection is showing as Private Network in windows