I don’t think there’s any official documentation for the web API, outside of this: Plex Open API Spec - #5 by elan, but from what I can tell that doesn’t include information on adding/removing friends. I’ve found it’s usually easiest to see what calls Python-PlexAPI makes (or just use it directly). E.g. the API call made to invite someone to your server is shown in the PlexAccount.inviteFriend method: plexapi.myplex — Python PlexAPI documentation (python-plexapi.readthedocs.io)
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