Do you mean this portion of the XML @ChuckPa ? (Edit: assuming so, pasting.)

<Media id="5680" duration="5652813" bitrate="11152" width="1920" height="1080" aspectRatio="1.78" audioChannels="6" audioCodec="dca-ma" videoCodec="h264" videoResolution="1080" container="mkv" videoFrameRate="24p" audioProfile="ma" videoProfile="high">
<Part accessible="1" exists="1" id="5680" key="/library/parts/5680/1417091643/file.mkv" duration="5652813" file="/mnt/media/movies/Near.Dark.1987.mkv" size="7888525401" audioProfile="ma" container="mkv" deepAnalysisVersion="6" requiredBandwidths="18379,17749,15984,13792,12509,12082,11461,11461" videoProfile="high">
<Stream id="12736" streamType="1" default="1" codec="h264" index="2" bitrate="8955" bitDepth="8" chromaLocation="left" chromaSubsampling="4:2:0" codedHeight="1088" codedWidth="1920" frameRate="23.976" hasScalingMatrix="0" height="1080" level="41" profile="high" refFrames="3" requiredBandwidths="15563,14933,13164,11113,9873,9449,9320,9320" scanType="progressive" width="1920" displayTitle="1080p (H.264)" extendedDisplayTitle="1080p (H.264)"> </Stream>
<Stream id="12737" streamType="2" selected="1" default="1" codec="dca" index="3" channels="6" bitrate="1548" language="English" languageTag="en" languageCode="eng" audioChannelLayout="5.1(side)" bitDepth="16" profile="ma" requiredBandwidths="1993,1850,1647,1647,1647,1647,1647,1647" samplingRate="48000" displayTitle="English (DTS-HD MA 5.1)" extendedDisplayTitle="English (DTS-HD MA 5.1)"> </Stream>
<Stream id="12738" streamType="2" codec="ac3" index="4" channels="6" bitrate="640" audioChannelLayout="5.1(side)" requiredBandwidths="640,640,640,640,640,640,640,640" samplingRate="48000" displayTitle="Unknown (AC3 5.1)" extendedDisplayTitle="Unknown (AC3 5.1)"> </Stream>
<Stream id="12734" streamType="3" default="1" codec="vobsub" index="0" bitrate="5" language="English" languageTag="en" languageCode="eng" headerCompression="1" requiredBandwidths="9,9,9,9,9,9,9,9" displayTitle="English (VOBSUB)" extendedDisplayTitle="English (VOBSUB)"> </Stream>
<Stream id="12735" streamType="3" codec="vobsub" index="1" bitrate="4" language="Dutch" languageTag="nl" languageCode="nld" headerCompression="1" requiredBandwidths="7,7,7,7,7,7,7,7" displayTitle="Dutch (VOBSUB)" extendedDisplayTitle="Dutch (VOBSUB)"> </Stream>
</Part>
</Media>
@Volts I can get you the file but let me look in that other thread first. A diagnosis is only for my own curiosity unless it might benefit a fix at Plex too–but if this is an ffmpeg issue then I guess the fix goes upstream.
It might just be a crummy file, too.