3 things, in the plex media server log.
there are quite a few ‘connection reset’ which may be network issues
afaik gemini man is a high frame rate 4k and causes problems, try a different movie if other movies play fine, you may be out of luck with this one
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Selected protocol hls; container: mkv
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: analyzing media item 893
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Gemini Man (2019): Direct Play is disabled
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Gemini Man (2019): media must be transcoded in order to use the hls protocol
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/truehd
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/dca
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.886 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/truehd
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/dca
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.887 [5806] DEBUG - MDE: Gemini Man (2019): no direct play video profile exists for http/mkv/hevc/ac3
May 21, 2020 20:23:49.888 [5806] DEBUG - MDE: Cannot direct stream audio stream due to codec truehd when profile only allows aac
May 21, 2020 20:23:49.888 [5806] DEBUG - MDE: Gemini Man (2019): selected media 0 / 893
May 21, 2020 20:23:49.888 [5806] ERROR - Streaming Resource: Cannot make a decision because either the file is unplayable or the client provided bad data
May 21, 2020 20:23:49.890 [5806] DEBUG - Streaming Resource: Reached Decision id=465 codes=(General=2000,Neither direct play nor conversion is available. Direct Play=3000,App cannot direct play this item. Direct play is disabled. Transcode=4002,Not enough CPU for conversion of this item.) media=(id=893 part=(id=893 decision=none container=mkv protocol=hls streams=(Video=(id=2401 decision=copy width=3840 height=2160) Audio=(id=2403 decision=transcode bitrate=774 encoder=aac channels=6 rate=48000))))
May 21, 2020 20:23:49.892 [3403] DEBUG - Completed: [192.168.0.148:36988] 200 GET /video/:/transcode/universal/decision?audioBoost=100&autoAdjustQuality=1&directPlay=0&directStream=1&directStreamAudio=1&fastSeek=1&hasMDE=1&location=lan&maxVideoBitrate=200000&mediaBufferSize=209664&mediaIndex=0&partIndex=0&path=%2Flibrary%2Fmetadata%2F465&protocol=*&session=b6223305c743cdca-com-plexapp-android&subtitleSize=100&videoBitrate=200000&videoQuality=100&videoResolution=3840x2160 (5 live) TLS GZIP 187ms 680 bytes (pipelined: 94)
basically from the log, it looks like the shield is unable to direct play the file, then it is transcoding, which most likely your server simply isn’t powerful enough to transcode 4k (it takes a huge ton of cpu to transcode 4k see FAQ link above). I don’t know if your nas supports gpu transcoding, but either way you don’t have plex pass so it wouldn’t work, and the whole point of 4k is to avoid transcoding in the first place.