PlexConnect/No Libraries

Your problem is different. You are using PlexConnect installed in a ATV3 and the latest python for that platform is 2.7.6, which cannot connect to plex.tv since Oct 1st, 2020. So you have 2 options:

  1. Parametrize PlexConnect to only use your local server (without plex.tv login)
  2. Install PlexConnect in another machine where you can install python 2.7.14 or later (2.7.18 recommended)

It’s a consequence of this announcement.