Verify your Plex Media Server version. It will be 1.x, not 4.x. Settings → Server_Name → General
or Authorized Devices
Synology model?
The Plex Media Server version provided by Synology is out of date. If you are using that version, download a current version from plex.tv and perform a manual update.
If you are running an old version of PMS, you are probably running into this problem: