Moved my music files to another harddrive and I now have two copies of every alblum?

How about swapping the drive letters of old and new drive?

To remove the unavailable albums, you need to edit the library, and remove the reference to the now empty/missing folder.

Another method would be to edit the database directly and replace all references to the old drive letter with the current drive letter. (Only for experienced users) [HowTo] Plex database modification - Moving media the right/wrong way