PMP Dual Screen Support – UI Controls on primary & video on secondary screen?

Install PMP for use on the main screen.
Then open a web browser on the second screen and open the Plex web app in it.
Connect the web app to PMP.
https://support.plex.tv/articles/categories/plex-apps/plex-companion/

If you install a WiFi access point, you could also use the Plex app on a mobile phone or tablet to do the same.