AAC should direct play. AAC should decode to another format (PCM, AC3, etc) on the FireStick, then pass over HDMI to attached TV/receiver/etc (based on how my AFTV Cube acts).
What is currently happening with the audio? Transcoding? If so, to what format?
Please pull the Plex XML, save as a text file, and attach to the thread. Alternately, analyze with MediaInfo and attach text output. See Investigate Media Information & Formats. Looking for info such as 5.1, 7.1, bitrate, depth, etc.
To what is the Fire stick attached - TV, receiver, etc? Make & model? Needed to check on supported audio formats (AC3, EAC3, PCM, etc).
How do you have the Fire Stick audio configured - the stick itself, not the Plex app? The exact working varies by FireStick device, but the options are generally 1) best available, 2) force AC3, 3) force EAC3, 4) force stereo.
Need to make sure the FireStick configuration aligns with the attached device (ex: don’t want FireStick forcing audio to EAC3 if it isn’t supported by attached tv/receiver/etc).
How do you have the Plex app audio configured? Is passthrough enabled? Ideally, set the audio & video to max/original quality (unsure of exact wording), and have passthrough enabled over HDMI.