I can't seem to get the extras to be recognized in Plex

From what you describe it sounds as if Plex is considering both files to be different (quality) versions of the same movie – not 1 movie and 1 related extra. That’s why Plex is even offering you the option to split the files apart.

How exactly did you organize/name your files?
The following two examples should work:

Movies   <- the folder linked to your movie library
  Movie Name (year)
    Movie Name (year).ext
    Behind the Scenes
      An interesting DVD extra.ext
Movies   <- the folder linked to your movie library
  Movie Name (year)
    Movie Name (year).ext
    An interesting DVD extra-behindthescenes.ext

Where .ext is a placeholder for your file extension.

After adding the files properly, you should only need to refresh the movie’s metadata for Plex to pick-up the extra. As the extra is now “known” to Plex as an actual movie, you’ll probably need to perform a full Plex Dance to make it forget and re-add it as an extra anew.