Is this about a Plex Media Server running on this Synology Disk Station or a Plex Media Server on a different platform (Linux, Windows, Mac), using the Synology NAS as its storage.
If you’re not seeing automatic scans for the Syno Server detecting changes on the NAS itself, you might have exceeded the number of folders the DSM is monitoring.
I believe there’s no user interface for this.
You’ll need to log into your NAS via SSH and execute some Linux commands.
you can run cat /proc/sys/fs/inotify/max_user_watches to get the current limit
you can change it following the procedure linked above
The support article also describes a way to get an accurate # of folders in your system.
For a finger-in-the-air estimate you can also take a look at the properties of your shares (via Synology File Station) and check the “Size” information (e.g. “3.31 GB (3,551,570,571 Bytes). Contain 184 file(s), 33 folder(s)”)