Then ones more, use NAS2NAS copy for all contents in the created share
After it finish, close PMS on both QNAP’s, and copy the directory /share/Plex/Plex Media Server/Plug-in Support/Databases to target QNAP, overwriting what’s there
Then delete the file named: /share/Plex/Plex Media Server/Preferences.xml on the target QNAP
Start Plex on both, and when browsing to target QNAP’s PMS, it should say it’s unclaimed