I’ve got more information 
mediainfo output:
General
Unique ID : 309131466222020742717079236360781172576 (0xE8908E046B52B3AB3F0FC1F43C7C0F60)
Complete name : Chernobyl.S01E01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE.mkv.crdownload
Format : Matroska
Format version : Version 4 / Version 2
File size : 347 MiB
Duration : 58mn 52s 3532sec
Overall bit rate : 824 Kbps
Encoded date : UTC 2019-05-28 13:31:38
Writing application : mkvmerge v20.0.0 ('I Am The Sun') 32-bit
Writing library : libebml v1.3.5 + libmatroska v1.4.8
IsTruncated : Yes
Video
ID : 1
Format : AVC
Format/Info : Advanced Video Codec
Format profile : High@L4
Format settings, CABAC : Yes
Format settings, ReFrames : 4 frames
Codec ID : V_MPEG4/ISO/AVC
Duration : 58mn 52s
Bit rate mode : Constant
Nominal bit rate : 10 000 Kbps
Width : 1 920 pixels
Height : 1 080 pixels
Display aspect ratio : 16:9
Frame rate mode : Constant
Frame rate : 11.905 fps
Color space : YUV
Chroma subsampling : 4:2:0
Bit depth : 8 bits
Scan type : Progressive
Bits/(Pixel*Frame) : 0.405
Default : Yes
Forced : No
Color range : Limited
Color primaries : BT.709
Transfer characteristics : BT.709
Matrix coefficients : BT.709
Audio #1
ID : 2
Format : AAC
Format/Info : Advanced Audio Codec
Format profile : LC
Codec ID : A_AAC
Duration : 58mn 52s
Channel(s) : 2 channels
Channel positions : Front: L R
Sampling rate : 48.0 KHz
Frame rate : 46.875 fps (1024 spf)
Compression mode : Lossy
Language : French
Default : Yes
Forced : No
Audio #2
ID : 3
Format : E-AC-3
Format/Info : Audio Coding 3
Format settings, Endianness : Big
Codec ID : A_EAC3
Duration : 58mn 52s
Bit rate mode : Constant
Bit rate : 640 Kbps
Channel(s) : 6 channels
Channel positions : Front: L C R, Side: L R, LFE
Sampling rate : 48.0 KHz
Frame rate : 187.500 fps (256 spf)
Compression mode : Lossy
Stream size : 270 MiB (78%)
Language : English
Default : No
Forced : No
Text #1
ID : 4
Format : UTF-8
Codec ID : S_TEXT/UTF8
Codec ID/Info : UTF-8 Plain Text
Title : Forced
Language : French
Default : Yes
Forced : Yes
Text #2
ID : 5
Format : UTF-8
Codec ID : S_TEXT/UTF8
Codec ID/Info : UTF-8 Plain Text
Language : French
Default : No
Forced : No
Text #3
ID : 6
Format : UTF-8
Codec ID : S_TEXT/UTF8
Codec ID/Info : UTF-8 Plain Text
Language : English
Default : No
Forced : No
And the logs from the Plex on the Synology ds214play when Direct Play is forced in PlexConnect settings (this one fails immediately when playing):
Sep 03, 2019 01:18:01.568 [0xaa3ffb40] DEBUG - Request: [192.168.1.15:52061 (Subnet)] GET /library/parts/8145/1565641298/file.mkv (4 live)
Sep 03, 2019 01:18:01.596 [0xaa3ffb40] DEBUG - Streaming Resource: Attempting to create AdHoc dp session for part 8145
Sep 03, 2019 01:18:01.649 [0xaa3ffb40] DEBUG - TranscodeUniversalRequest: using profile Generic
Sep 03, 2019 01:18:01.651 [0xaa3ffb40] DEBUG - Downloading document http://127.0.0.1:32400/library/metadata/7473?includeBandwidths=1&offset=-1&X-Plex-Session-Identifier=token%3D
Sep 03, 2019 01:18:01.651 [0xaa3ffb40] DEBUG - HTTP requesting GET http://127.0.0.1:32400/library/metadata/7473?includeBandwidths=1&offset=-1&X-Plex-Session-Identifier=token%3D
Sep 03, 2019 01:18:01.655 [0xaae23b40] DEBUG - Request: [127.0.0.1:44520 (Loopback)] GET /library/metadata/7473?includeBandwidths=1&offset=-1 (5 live) GZIP
Sep 03, 2019 01:18:01.682 [0xaae23b40] DEBUG - We're going to try to auto-select an audio stream for account 1.
Sep 03, 2019 01:18:01.682 [0xaae23b40] DEBUG - Selecting best audio stream for part ID 8145 (autoselect: 1 language: fr)
Sep 03, 2019 01:18:01.682 [0xaae23b40] DEBUG - We're going to try to auto-select a subtitle.
Sep 03, 2019 01:18:01.682 [0xaae23b40] DEBUG - Found a forced subtitle which matched account language
Sep 03, 2019 01:18:01.682 [0xaae23b40] DEBUG - Audio Stream: 25419, Subtitle Stream: 25421
Sep 03, 2019 01:18:01.686 [0xb2f11b40] DEBUG - Completed: [127.0.0.1:44520] 200 GET /library/metadata/7473?includeBandwidths=1&offset=-1 (5 live) GZIP 31ms 1895 bytes
Sep 03, 2019 01:18:01.686 [0xaa3ffb40] DEBUG - HTTP 200 response from GET http://127.0.0.1:32400/library/metadata/7473?includeBandwidths=1&offset=-1&X-Plex-Session-Identifier=token%3D
Sep 03, 2019 01:18:01.694 [0xaa3ffb40] DEBUG - MDE: received PLEX_PROTOCOL_ANY from client, but could not determine best protocol. Defaulting to HTTP
Sep 03, 2019 01:18:01.694 [0xaa3ffb40] DEBUG - MDE: analyzing media item 7537
Sep 03, 2019 01:18:01.695 [0xaa3ffb40] DEBUG - MDE: E2 - Veuillez garder votre calme: Direct Playing due to no transcode profile
Sep 03, 2019 01:18:01.695 [0xaa3ffb40] DEBUG - MDE: E2 - Veuillez garder votre calme: no direct play video profile exists for http/mkv/h264
Sep 03, 2019 01:18:01.695 [0xaa3ffb40] DEBUG - MDE: E2 - Veuillez garder votre calme: no direct play video profile exists for http/mkv/h264/aac
Sep 03, 2019 01:18:01.695 [0xaa3ffb40] DEBUG - MDE: E2 - Veuillez garder votre calme: no direct play video profile exists for http/mkv/h264/eac3
Sep 03, 2019 01:18:01.696 [0xaa3ffb40] DEBUG - MDE: Chernobyl - S1 E2 - Veuillez garder votre calme: selected media 0 / 7537
Sep 03, 2019 01:18:01.696 [0xaa3ffb40] DEBUG - Streaming Resource: Added session 0xabc3d0d4:token=
Sep 03, 2019 01:18:01.696 [0xaa3ffb40] DEBUG - Streaming Resource: Reached Decision id=7473 codes=(MDE=1000,Direct play OK.) media=(id=7537 part=(id=8145 decision=direct play protocol=* streams=(Video=(id=25418 decision= width=0 height=0) Audio=(id=25419 decision= channels=0 rate=0) Subtitle=(id=25421 decision=unavailable languageCode=fre location=sidecar))))
Sep 03, 2019 01:18:01.697 [0xaa3ffb40] DEBUG - Content-Length of /volume1/Chernobyl.S01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E02.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E02.MULTi.1080p.AMZN.WEB-DL.H264-NoNE.mkv is 4819328582.
Sep 03, 2019 01:18:01.717 [0xb2f11b40] DEBUG - Completed: [192.168.1.15:52061] 200 GET /library/parts/8145/1565641298/file.mkv (5 live) 150ms 2 bytes (pipelined: 1) (range: bytes=0-1)
Sep 03, 2019 01:18:01.758 [0xac7ffb40] DEBUG - Request: [192.168.1.15:52061 (Subnet)] GET /library/parts/8145/1565641298/file.mkv (4 live)
Sep 03, 2019 01:18:01.775 [0xac7ffb40] DEBUG - Content-Length of /volume1/Chernobyl.S01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E02.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E02.MULTi.1080p.AMZN.WEB-DL.H264-NoNE.mkv is 4819328582.
Sep 03, 2019 01:18:01.822 [0xb2f11b40] DEBUG - Failed to stream media, client probably disconnected after 218648 bytes: 32 - Broken pipe
Sep 03, 2019 01:18:01.822 [0xb2f11b40] DEBUG - Completed: [192.168.1.15:52061] 200 GET /library/parts/8145/1565641298/file.mkv (4 live) 65ms 218648 bytes (pipelined: 2) (range: bytes=0-4819328581)
Sep 03, 2019 01:18:01.838 [0xaae23b40] DEBUG - Request: [192.168.1.15:52062 (Subnet)] GET /library/parts/8145/1565641298/file.mkv (5 live)
Sep 03, 2019 01:18:01.855 [0xaae23b40] DEBUG - Content-Length of /volume1/Chernobyl.S01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E02.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E02.MULTi.1080p.AMZN.WEB-DL.H264-NoNE.mkv is 4819328582.
Sep 03, 2019 01:18:02.117 [0xb2f11b40] DEBUG - Failed to stream media, client probably disconnected after 1026632 bytes: 104 - Connection reset by peer
And this output is when I set the Transcoding to Auto in the PlexConnect app:
Sep 02, 2019 23:47:12.627 [0xab3ffb40] DEBUG - Request: [192.168.1.15:51201 (Subnet)] GET /video/:/transcode/universal/start.m3u8?maxVideoBitrate=40000&videoQuality=100&subtitleSize=100&mediaBufferSize=80000&partIndex=0&session=DY3L88KNFF54&skipSubtitles=0&audioBoost=100&protocol=hls&path=%2Flibrary%2Fmetadata%2F7472&videoResolution=1920x1080&fastSeek=1&directStream=1 (12 live) GZIP
Sep 02, 2019 23:47:12.628 [0xab3ffb40] DEBUG - Found session GUID of DY3L88KNFF54 in session start.
Sep 02, 2019 23:47:12.659 [0xab3ffb40] DEBUG - TranscodeUniversalRequest: using augmented profile iOS
Sep 02, 2019 23:47:12.662 [0xab3ffb40] DEBUG - Downloading document http://127.0.0.1:32400/library/metadata/7472?checkFiles=1&includeBandwidths=1&offset=-1&X-Plex-Client-Capabilities=protocols%3Dhttp-live-streaming%2Chttp-mp4-streaming%2Chttp-streaming-video%2Chttp-streaming-video-720p%2Chttp-mp4-video%2Chttp-mp4-video-720p;videoDecoders%3Dh264{profile%3Ahigh%26resolution%3A1080%26level%3A41};audioDecoders%3Dmp3%2Caac{bitrate%3A160000}&X-Plex-Session-Identifier=DY3L88KNFF54
Sep 02, 2019 23:47:12.770 [0xab3ffb40] DEBUG - We're going to try to auto-select an audio stream for account 1.
Sep 02, 2019 23:47:12.770 [0xab3ffb40] DEBUG - Selecting best audio stream for part ID 8144 (autoselect: 1 language: fr)
Sep 02, 2019 23:47:12.770 [0xab3ffb40] DEBUG - We're going to try to auto-select a subtitle.
Sep 02, 2019 23:47:12.770 [0xab3ffb40] DEBUG - Found a forced subtitle which matched account language
Sep 02, 2019 23:47:12.770 [0xab3ffb40] DEBUG - Audio Stream: 25413, Subtitle Stream: 25415
Sep 02, 2019 23:47:12.775 [0xab3ffb40] DEBUG - Streaming Resource: Attempting to create AdHoc transcode session DY3L88KNFF54
Sep 02, 2019 23:47:12.779 [0xab3ffb40] DEBUG - Scaled up video bitrate to 13815Kbps based on 1.500000x fudge factor.
Sep 02, 2019 23:47:12.780 [0xab3ffb40] DEBUG - MDE: Selected protocol hls; container: mpegts
Sep 02, 2019 23:47:12.781 [0xab3ffb40] DEBUG - MDE: analyzing media item 7536
Sep 02, 2019 23:47:12.781 [0xab3ffb40] DEBUG - MDE: E1 - 1:23:45: Direct Play is disabled
Sep 02, 2019 23:47:12.781 [0xab3ffb40] DEBUG - MDE: E1 - 1:23:45: media must be transcoded in order to use the hls protocol
Sep 02, 2019 23:47:12.781 [0xab3ffb40] DEBUG - MDE: E1 - 1:23:45: selected subtitle cannot be converted to a compatible format, burning into video stream
Sep 02, 2019 23:47:12.782 [0xab3ffb40] DEBUG - MDE: E1 - 1:23:45: avoiding video remux due to burned subtitle stream
Sep 02, 2019 23:47:12.782 [0xab3ffb40] DEBUG - MDE: E1 - 1:23:45: no remuxable profile found, so video stream will be transcoded
Sep 02, 2019 23:47:12.782 [0xab3ffb40] DEBUG - MDE: Cannot direct stream video stream due to profile or setting limitations
Sep 02, 2019 23:47:12.782 [0xab3ffb40] DEBUG - Scaled up video bitrate to 13815Kbps based on 1.500000x fudge factor.
Sep 02, 2019 23:47:12.783 [0xab3ffb40] DEBUG - MDE: Chernobyl - S1 E1 - 1:23:45: selected media 0 / 7536
Sep 02, 2019 23:47:12.784 [0xab3ffb40] DEBUG - Streaming Resource: Adding session 0xaa4b40d4:DY3L88KNFF54 which is using transcoder slot. Used slots is now 1
Sep 02, 2019 23:47:12.784 [0xab3ffb40] DEBUG - Streaming Resource: Added session 0xaa4b40d4:DY3L88KNFF54
Sep 02, 2019 23:47:12.784 [0xab3ffb40] DEBUG - Streaming Resource: Reached Decision id=7472 codes=(General=1001,Direct play not available; Conversion OK. Direct Play=3000,App cannot direct play this item. Direct play is disabled. Transcode=1001,Direct play not available; Conversion OK.) media=(id=7536 part=(id=8144 decision=transcode container=mpegts protocol=hls streams=(Video=(id=25412 decision=transcode bitrate=13815 encoder=libx264 width=1920 height=1080) Audio=(id=25413 decision=copy channels=2 rate=48000) Subtitle=(id=25415 decision=burn languageCode=fre location=embedded))))
Sep 02, 2019 23:47:12.784 [0xab3ffb40] DEBUG - Found session GUID of DY3L88KNFF54 in session start.
Sep 02, 2019 23:47:12.784 [0xab3ffb40] DEBUG - Using session GUID DY3L88KNFF54 for new transcode session.
Sep 02, 2019 23:47:12.785 [0xab3ffb40] DEBUG - Cleaning directory for session DY3L88KNFF54 ()
Sep 02, 2019 23:47:12.819 [0xb1bffb40] DEBUG - Completed: [192.168.1.15:51201] 200 GET /video/:/transcode/universal/start.m3u8?maxVideoBitrate=40000&videoQuality=100&subtitleSize=100&mediaBufferSize=80000&partIndex=0&session=DY3L88KNFF54&skipSubtitles=0&audioBoost=100&protocol=hls&path=%2Flibrary%2Fmetadata%2F7472&videoResolution=1920x1080&fastSeek=1&directStream=1 (12 live) GZIP 192ms 464 bytes (pipelined: 1)
Sep 02, 2019 23:47:12.852 [0xac511b40] DEBUG - Request: [192.168.1.15:51201 (Subnet)] GET /video/:/transcode/universal/session/DY3L88KNFF54/base/index.m3u8 (12 live) GZIP
Sep 02, 2019 23:47:12.853 [0xac511b40] DEBUG - Found session GUID of DY3L88KNFF54 in session start.
Sep 02, 2019 23:47:12.853 [0xac511b40] DEBUG - Starting a transcode session DY3L88KNFF54 at offset -1.0 (state=3)
Sep 02, 2019 23:47:12.878 [0xac511b40] DEBUG - [Universal] Using local file path instead of URL: /volume1/video/TV show/adultes/all/Chernobyl.S01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE.mkv
Sep 02, 2019 23:47:12.879 [0xac511b40] DEBUG - TPU: hardware transcoding: zero-copy support not present
Sep 02, 2019 23:47:12.885 [0xac511b40] DEBUG - Job running: EAE_ROOT='/volume1/Plex/tmp_transcoding/pms-0ca66d1e-5c02-4bbd-97c0-6569a0c884d5/EasyAudioEncoder' FFMPEG_EXTERNAL_LIBS='/volume1/Plex/Library/Application\ Support/Plex\ Media\ Server/Codecs/e944d3a-1309-linux-synology-i686/' XDG_CACHE_HOME='/volume1/Plex/Library/Application Support/Plex Media Server/Cache' XDG_DATA_HOME='/volume1/@appstore/Plex Media Server/Resources' '/volume1/@appstore/Plex Media Server/Plex Transcoder' '-codec:0' 'h264' '-i' '/volume1/Chernobyl.S01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE/Chernobyl.S01E01.MULTi.1080p.AMZN.WEB-DL.H264-NoNE.mkv' '-map_inlineass' '0:3' '-filter_complex' '[0:0]scale=w=1920:h=1080[0];[0]format=pix_fmts=yuv420p|nv12[1];[1]inlineass=font_scale=1.000000:font_path=/volume1/@appstore/Plex\\\ Media\\\ Server/Resources/Fonts/DejaVuSans-Regular.ttf:fontconfig_file=/volume1/@appstore/Plex\\\ Media\\\ Server/Resources/fonts.conf[2]' '-map' '[2]' '-codec:0' 'libx264' '-crf:0' '16' '-maxrate:0' '13815k' '-bufsize:0' '27630k' '-r:0' '23.809999999999999' '-preset:0' 'veryfast' '-x264opts:0' 'subme=0:me_range=4:rc_lookahead=10:me=dia:no_chroma_me:8x8dct=0:partitions=none' '-force_key_frames:0' 'expr:gte(t,0+n_forced*1)' '-map' '0:1' '-metadata:s:1' 'language=fre' '-codec:1' 'copy' '-copypriorss:1' '0' '-segment_format' 'mpegts' '-f' 'ssegment' '-individual_header_trailer' '0' '-segment_time' '1' '-segment_start_number' '0' '-segment_copyts' '1' '-segment_time_delta' '0.0625' '-segment_list' 'http://127.0.0.1:32400/video/:/transcode/session/DY3L88KNFF54/976118c2-12af-4c91-bb26-c80b6a3c9b5e/seglist' '-segment_list_type' 'csv' '-segment_list_size' '2147483647' '-segment_list_separate_stream_times' '1' '-max_delay' '5000000' '-avoid_negative_ts' 'disabled' '-map_metadata' '-1' '-map_chapters' '-1' 'media-%05d.ts' '-map' '0:3' '-f' 'null' '-codec' 'ass' 'nullfile' '-start_at_zero' '-copyts' '-vsync' 'cfr' '-y' '-nostats' '-loglevel' 'quiet' '-loglevel_plex' 'error' '-progressurl' 'http://127.0.0.1:32400/video/:/transcode/session/DY3L88KNFF54/976118c2-12af-4c91-bb26-c80b6a3c9b5e/progress'
Sep 02, 2019 23:47:12.889 [0xac511b40] DEBUG - Jobs: Starting child process with pid 1326
Why is the direct play failing?
The Auto mode forces the transcoding in order to burn the subtitles to the video. Is that right? Is there a way to disable “Forced” subtitles? I will enable them when needed.
Thanks