Plex won't "forget" a movie after it is deleted (so I can re-add it with new chapter stop names)

My next step I’d do is Plex dance every copy of the video all at once. Since Plex loves to lump every copy of a video together, it might use one set of data for tags, such as chapter titles, even though alternate files have different info… Do the dance to do a fresh start, make Plex load everything all over again.

So remove all copies from the library location. re-scan library. empty trash. clean bundle. Then add the files one-by-one, with a fresh scan between each add.