Samsung series 6 not working. Black screen on play

Important information about Plex for smart TVs after September 30, 2021 - Announcements - Plex Forum

That may be your answer. If it isn’t, we are going to need way more info. What app version are you using, what specific model of TV, what is the server version, server logs, and probably the media info of the file you are trying to play also.