Changed PW & add Full Name. Now instead opening Desktop app, it is using Web App. Server on DT only

Changing your password unclaims the server. You need to re-claim it.

If you’re on the server, go to http://127.0.0.1:32400/web. Then go to Settings → Server_Name → General and claim the server.

If you are on a different system but on the same network, use the IP address of the server. For example, if the IP address is 10.1.2.3, use http://10.1.2.3:32400/web.

Claiming the server registers it with your account at plex.tv. Once it is claimed, you should be able to access it via https://app.plex.tv/desktop.

EDIT: If the above does not work, see the following:

You need to reclaim your server, but don’t dare to touch the Windows Registry

Why am I locked out of Server Settings and how do I get in?