I’m relatively new to plex so can’t provide much in the way of technical guidance I’m afraid.
Plex should be transcoding the DTS, so might be worth seeing what is being output. Should show something like Transcode DTS > AC3.
I figured it out with some help, Just go into the settings of the LG Plex app and disable DTS. The server will then transcode.
In my case i had to reinstall plex because on my Synology DS218+ Nas hardware acceleration wasn’t working what appeared to be a common problem after a DSM update.
Only thing is that it is transcoding not only DTS but also Atmos en other HD autio formats. Dolby Digital AC3 does directplay.