Newly added TV shows not showing in PMS

You may want to try compliant file names and structures for TV Shows:
https://support.plex.tv/articles/naming-and-organizing-your-tv-show-files/

Then you may want to demote LMA for Shows and Movies (all tabs) so Plex will stop preferring embedded and bogus Title Fields in your MP4 files - over any file names and missing structure elements you may have - or not have:

There’s nothing preventing the matching of this one that I can see - in this test:

A TV Show Library Folder\ <---TV Show Library 'Add Folders' aimed here - ONLY
....The Salisbury Poisonings\
........Season 01\
.............The Salisbury Poisonings - S01E01.mp4
.............The Salisbury Poisonings - S01E02.mp4
.............The Salisbury Poisonings - S01E03.mp4

'Cause that results instantly and naturally as: