We could make some progress I hope with
- your exact PMS server version.
- your QTS version
- a basic description of your network
- screenshots of all the QNAP advanced
Network & Virtual Switchpages, but go ahead and redact your WAN IP - tell us the IP address of your player device on the LAN.
- what things you tried from The QNAP FAQ for Plex.
- Can you SSH into it and look at the logs for something obvious?
ssh -l admin xxx.xxx.xxx.xxx
cd "`getcfg -f /etc/config/qpkg.conf PlexMediaServer Install_path`/Library/Plex Media Server/Logs"