I am having a very hard time with this thread at the technical level.
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The plex version you list is a Windows version for the Windows systems. QNAP is Linux. Linux file systems and Windows file systems are structured completely differently as well as all the storage locations are different.
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I will not attempt to speak to Windows . I do not own Windows nor do I understand it beyond a very basic level. I have never installed Plex on a Windows system.
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To backup your Plex Server’s internal data (all the metadata and databases) as a full, self-standing, image backup which captures PMS at that instant in time,
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Also listed below is how to restore your Plex server instance and all its data.
Please tell me what didn’t work?