Ding Ding! we have a winner!
So you are running into a very common human error. your show is located at /share/Storage Vault/TV Shows/M/Ms. Marvel (2022) however you added /share/Storage Vault/TV Shows to your library.
So you have 2 options, remove the M directory (and I am assuming directories for each letter) or remove /share/Storage Vault/TV Shows and add /share/Storage Vault/TV Shows/A thru /share/Storage Vault/TV Shows/Z
EDIT: I am going to bet if you start looking for duplicates in your library you will see a LOT of them. Plex does not handle extra directories well.
