Plex Files Unavailable but they’re not missing

this does sound like a different issue, your issue sounds like doing the plex dance may be your better option. Or trying the empty library trash, as they will stay there until trash is emptied, either as the schedule task or manually if you have that turned off.

the issue on this thread is related to SMB mounts basically not being kept alive or being woken back up by Mac for Plex.