Plex no longer connects to my Plex Media Server on Synology NAS!

Are you actually using the server’s local IP address (no own URLs or any Syno remote-connect URLs)? Are you inside the same subnet?

I assume you recently reset your account password and opted to sign-out all devices? This should also sign-out / unclaim the server – though you should still be able to access it locally. If bad comes to worse, you should be able to reclaim the server using this script: