I’ll need to get back with the iOS player settings, as my daughter doesn’t want to give me the iPad at the moment 
Android Player Settings
- Video Quality - Home Streaming - Videos will play at maximum quaility
- Audio boost - None
- H264 maximum level - 4.1 (Recommended)
- Audio passthrough - Disabled
- Optional Audio Support - None
- Use Android media player - Disabled
- Use external player - Disabled
Example video #1
<MediaContainer size="1" allowSync="1" identifier="com.plexapp.plugins.library" librarySectionID="6" librarySectionTitle="Movies - Sophie" librarySectionUUID="ff277aa7-9ab9-4f72-8539-2c2b17677fbb" mediaTagPrefix="/system/bundle/media/flags/" mediaTagVersion="1534565707">
<Video ratingKey="30675" key="/library/metadata/30675" guid="com.plexapp.agents.imdb://tt3655680?lang=en" librarySectionTitle="Movies - Sophie" librarySectionID="6" librarySectionKey="/library/sections/6" type="movie" title="Thomas & Friends: Sodor's Legend of the Lost Treasure: The Movie" contentRating="Not Rated" summary="Shiver me timbers. Surprises await Thomas and his friends as they dig up their most daring adventure yet. Unearthing an old pirate ship, Thomas is on the hunt for Sodor's lost treasure. When Thomas rocks the boat with some new friends, trouble soon rushes in. Will Thomas track down the treasure in time, or will Sailor John set sail with it? Join Thomas and Friends in this explosive movie adventure." rating="8.0" audienceRating="6.8" year="2015" thumb="/library/metadata/30675/thumb/1534227983" art="/library/metadata/30675/art/1534227983" duration="3778025" originallyAvailableAt="2015-07-17" addedAt="1533862660" updatedAt="1534227983" audienceRatingImage="rottentomatoes://image.rating.spilled" chapterSource="media" ratingImage="rottentomatoes://image.rating.ripe">
<Media videoResolution="480" id="35467" duration="3778025" bitrate="1475" width="720" height="480" aspectRatio="1.78" audioChannels="6" audioCodec="ac3" videoCodec="h264" container="mp4" videoFrameRate="24p" optimizedForStreaming="0" has64bitOffsets="0" videoProfile="high">
<Part accessible="1" exists="1" id="35548" key="/library/parts/35548/1529047645/file.m4v" duration="3778025" file="/volume1/video/Sophie's Shows/Movies/Thomas And Friends - Legend Of The Lost Treasure.m4v" size="696643252" container="mp4" deepAnalysisVersion="2" has64bitOffsets="0" optimizedForStreaming="0" requiredBandwidths="2852,2749,2749,2749,2749,2749,2749,2749" videoProfile="high">
<Stream id="25641" streamType="1" default="1" codec="h264" index="0" bitrate="1023" anamorphic="1" bitDepth="8" chromaLocation="left" chromaSubsampling="4:2:0" colorPrimaries="smpte170m" colorRange="tv" colorSpace="smpte170m" colorTrc="bt709" frameRate="23.976" hasScalingMatrix="0" height="480" level="40" pixelAspectRatio="32:27" profile="high" refFrames="5" requiredBandwidths="2404,2324,2324,2324,2324,2324,2324,2324" streamIdentifier="1" width="720" displayTitle="Unknown (H.264 High)"/>
<Stream id="25642" streamType="2" selected="1" default="1" codec="ac3" index="1" channels="6" bitrate="448" language="English" languageCode="eng" audioChannelLayout="5.1(side)" requiredBandwidths="448,448,448,448,448,448,448,448" samplingRate="48000" streamIdentifier="2" displayTitle="English (AC3 5.1(side))"/>
</Part>
</Media>
<Genre id="23" filter="genre=23" tag="Animation"/>
<Genre id="25" filter="genre=25" tag="Adventure"/>
<Genre id="26" filter="genre=26" tag="Comedy"/>
<Genre id="27" filter="genre=27" tag="Family"/>
<Genre id="52" filter="genre=52" tag="Fantasy"/>
<Director id="45865" filter="director=45865" tag="David Stoten"/>
<Country id="920" filter="country=920" tag="United Kingdom"/>
<Role id="46393" filter="actor=46393" tag="Eddie Redmayne" role="Ryan" thumb="http://image.tmdb.org/t/p/original/bHipa1GkpedD32w2OIRg5axdkQ6.jpg"/>
<Role id="8406" filter="actor=8406" tag="John Hurt" role="Sailor John" thumb="http://image.tmdb.org/t/p/original/rpuH2YRLpxJjMxHq4T1QdOSVtlN.jpg"/>
<Role id="8431" filter="actor=8431" tag="Jamie Campbell Bower" role="Skiff" thumb="http://image.tmdb.org/t/p/original/wzuENDUCak8HKRh72Jj7p3BQ7NY.jpg"/>
<Role id="5121" filter="actor=5121" tag="Olivia Colman" role="Marion" thumb="http://image.tmdb.org/t/p/original/3lcPisWEYVcDq09mFrqni3Nao0C.jpg"/>
<Role id="46399" filter="actor=46399" tag="Steven Kynman" role="Duck"/>
<Role id="46398" filter="actor=46398" tag="Nathan Clarke" role="Alfie"/>
<Role id="45883" filter="actor=45883" tag="Keith Wickham" role="Several characters" thumb="http://image.tmdb.org/t/p/original/4cBCajgznRpIDJ2ndvHMccOsEcV.jpg"/>
<Role id="45494" filter="actor=45494" tag="Teresa Gallagher" role="Emily, Daisy, Annie and Clarabel"/>
<Role id="45883" filter="actor=45883" tag="Keith Wickham" role="Edward, Henry, Gordon, James, Percy, Salty, Bert, Bertie and Sir Topham Hatt" thumb="http://image.tmdb.org/t/p/original/4cBCajgznRpIDJ2ndvHMccOsEcV.jpg"/>
<Role id="45885" filter="actor=45885" tag="Mark Moraghan" role="Narrator" thumb="http://image.tmdb.org/t/p/original/u7yVP128uK3xL1nj3dBwNbi0ItA.jpg"/>
<Role id="46392" filter="actor=46392" tag="David Bedella" role="Victor"/>
<Role id="46400" filter="actor=46400" tag="Tom Stourton" role="Rex" thumb="http://image.tmdb.org/t/p/original/1fUBK2bbdNOVXnzSlRKfXPvGmxD.jpg"/>
<Role id="45887" filter="actor=45887" tag="Rob Rackstraw" role="Toby"/>
<Role id="45895" filter="actor=45895" tag="Tim Whitnall" role="Mike and Oliver"/>
<Role id="46396" filter="actor=46396" tag="Jonathan Broadbent" role="Bill and Ben"/>
<Role id="46397" filter="actor=46397" tag="Matt Wilkinson" role="Cranky and Kevin"/>
<Role id="46394" filter="actor=46394" tag="Joe Mills" role="Donald, Douglas, Oliver and Toad"/>
<Role id="46395" filter="actor=46395" tag="John Hasler" role="Thomas (voice)"/>
<Extras size="0"> </Extras>
</Video>
</MediaContainer>
Example video #2
<MediaContainer size="1" allowSync="1" identifier="com.plexapp.plugins.library" librarySectionID="5" librarySectionTitle="TV Shows - Sophie" librarySectionUUID="30fa0942-0a53-4b0f-b0b3-9d5907a32b7a" mediaTagPrefix="/system/bundle/media/flags/" mediaTagVersion="1534565707">
<Video ratingKey="31722" key="/library/metadata/31722" parentRatingKey="31645" grandparentRatingKey="31644" guid="com.plexapp.agents.thetvdb://267108/1/27?lang=en" librarySectionTitle="TV Shows - Sophie" librarySectionID="5" librarySectionKey="/library/sections/5" type="episode" title="Slow Quest" grandparentKey="/library/metadata/31644" parentKey="/library/metadata/31645" grandparentTitle="Sarah & Duck" parentTitle="Season 1" contentRating="TV-Y" summary="Tortoise is on a mission straight through Sarah and Duck’s house! The pair try to work out what he’s crawling towards." index="27" parentIndex="1" year="2013" thumb="/library/metadata/31722/thumb/1534208779" art="/library/metadata/31644/art/1534208801" parentThumb="/library/metadata/31645/thumb/1534208801" grandparentThumb="/library/metadata/31644/thumb/1534208801" grandparentArt="/library/metadata/31644/art/1534208801" grandparentTheme="/library/metadata/31644/theme/1534208801" duration="419320" originallyAvailableAt="2013-08-20" addedAt="1534125344" updatedAt="1534208779">
<Media videoResolution="1080" id="37734" duration="419320" bitrate="1118" width="1920" height="1080" aspectRatio="1.78" audioChannels="2" audioCodec="ac3" videoCodec="hevc" container="mkv" videoProfile="main">
<Part accessible="1" exists="1" id="37896" key="/library/parts/37896/1515600681/file.mkv" duration="419320" file="/volume1/video/Sophie's Shows/Sarah and Duck/Sarah & Duck - 2013 08 20 - 1x27 - Slow Quest.mkv" size="58614519" container="mkv" deepAnalysisVersion="2" requiredBandwidths="1108,1108,1108,1108,1108,1108,1108,1108" videoProfile="main">
<Stream id="31181" streamType="1" default="1" codec="hevc" index="0" bitrate="926" bitDepth="8" chromaSubsampling="4:2:0" colorRange="tv" frameRate="50.000" height="1080" level="150" profile="main" refFrames="1" requiredBandwidths="919,919,919,919,919,919,919,919" width="1920" displayTitle="Unknown (HEVC Main)"/>
<Stream id="31182" streamType="2" selected="1" default="1" codec="ac3" index="1" channels="2" bitrate="192" audioChannelLayout="stereo" requiredBandwidths="190,190,190,190,190,190,190,190" samplingRate="48000" displayTitle="Unknown (AC3 Stereo)"/>
</Part>
</Media>
<Extras size="0"> </Extras>
</Video>
</MediaContainer>
EDIT:
I should mention that it seems to be able to happen on pretty much any video. These are the most recent which had problems.