Can not install PMS on Synology DS3622xs+ (DSM7.2.2-72806)

First of all, migrating from DSM 6 → DSM 7 is not straight forward, so you will need to follow the instructions found here:

When you are ready to install Plex, you need to download the Plex package that is intended specifically for DSM 7.2.2+.

You will find that on the Plex Downloads page.