HELP - Trantranscoder Error

Well, you are running in Verbose mode, and suggest you disable that.

When said, your movie is transcoding audio from TrueHD, since that’s not supported by your Titzen TV
( Ref: 2018 TV Video Specifications | Samsung Developers )

And an audio transcode does not use a GPU, only a CPU

Also the subtitle has to be burned in, since not in a proper format (PGS)

MDE: Dune (2021): selected subtitle cannot be converted to a compatible format, burning into video stream

All I can suggest here, is to remux the Audio track into something supported by your TV, and also consider finding another subtitle, in like srt format
(You could also test playing without subs, and see if that makes a difference)

For some nice 4K info, read this post:

P.S. Plex is still using the onboard Intel QuickSync, so did you install the GPU drivers?