You must name things correctly. After you name and organize correctly, Plex Dance the entire show to clear the incorrect information from the Plex database.
Wrong (from your log files):
/volume1/benthien2007/Tv/MCU - Tv/Loki.Season 1/Loki.S01E06.mkv
/volume1/benthien2007/Tv/MCU - Tv/The.Falcon.and.the.Winter.Soldier.S01.1080p.WEB-DL.x265.10Bit.6CH-Pahe.in/The.Falcon.and.The.Winter.Soldier.S01E06.One.World.One.People.1080p.WEB-DL.x265.10Bit.6CH-Pahe.in.mkv
Correct:
/volume1/benthien2007/Tv/MCU - Tv/ <-- TV Library MUST point here, not at .../Tv
.../Loki <-- Every show in its own directory
....../Season 01 <--"Season" in English, two digits for season number
.........Loki - s01e06.mkv <-- Naming per Plex documentation
.../The Falcon and the Winter Soldier
....../Season 01
........./The Falcon and the Winter Soldier - s01e06.mkv
