Seems similar to this reddit post. The most likely answer is that some random user/bot hit your Plex domain/IP:Port, so your server provided the static web app content (HTML/CSS/JS), which is about 6MB. They should have then been redirected to plex.tv for authentication, and they won’t be able to access any of your actual server content unless they’re authorized to do so.
Actually, digging into the IP, it looks like that’s a Plex Relay server (relay09.pop.lhr.plex.bz), so it could be that you/someone you share with wasn’t able to make a direct connection to your server, so it was routed through Relay.