Web Hooks not showing on the QNAP Plex App

The bundled web-client is VERY old!

3.57.1 was released june 2018

Ref: Plex Web

As such, I suspect your PMS version is also old, but sadly you didn’t say what version

And assume, that when using local PC, you access the online version of the Web-Client, found here: https://app.plex.tv/desktop