All of my libraries on QNAP are missing and no server settings

See this: Qnap faq.....read me first! - #5 by ChuckPa

This would allow you to access the plexdata share, which also gives access to the logs

But since you mentioned a new router, I suspect that your QNAP simply can’t access the internet, so from QNAP QTS, check that your IP, default router and your DNS settings are okay