Content of my NAS is not visible

You are using Synology QuickConnect. (the .me domain name)

This causes Plex/web to be cautious. You gave it an IP address but got a domain name response.

It is giving you a one-time warning.

As for movie content not being available, Does PlexMediaServer have full permission to read the media shared folder, sub-folders, and files?

This is a common oversight because of how much DSM 7 changed